Polyacrylonitrile copolymer, polyacrylonitrile precursor fiber for carbon fiber, carbon bundles, fabricating method of flame retardant bundles and fabricating method of carbon bundles

Provided are: a polyacrylonitrile-based precursor fiber for the production of a carbon fiber having a large single-fiber fineness, said precursor fiber ensuring high heat stability of a spinning dope and excellent productivity; and a copolymer suitable for the production of said precursor fiber. Als...

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Hauptverfasser: AOYAMA, NAOKI, HIROTA, NORIFUMI, MATSUYAMA, NAOMASA, FUJII, YASUYUKI, SHINMEN, YUSUKE, NII, TAKESHI, IRIE, YOSHIKO, MATSUDA, HARUMI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:Provided are: a polyacrylonitrile-based precursor fiber for the production of a carbon fiber having a large single-fiber fineness, said precursor fiber ensuring high heat stability of a spinning dope and excellent productivity; and a copolymer suitable for the production of said precursor fiber. Also provided are: high-quality carbon fiber bundles which have a large single-fiber fineness and excellent productivity; a process for producing the same; and a process for producing flameproofed fiber bundles suitable for the production of the carbon fiber bundles. A polyacrylonitrile-based copolymer which comprises 93.0 to 99.4 mol% of acrylonitrile units, 0.5 to 4.0 mol% of (meth)acrylamide -based units, and 0.1 to 3.0 mol% of unsaturated carboxylic acid hydroxyalkyl ester units and in which the (meth)acrylamide-based units are (meth)acrylamide units and/or (meth)acrylamide derivative units having a molecular weight of 105 or less; a precursor fiber comprising the copolymer; a process for producing flameproofed fi