Heat stable photocurable resin composition for dry film resist

The invention relates to a process for preparing a dry film resist by forming a photocurable resin composition onto a support film with a thickness of 1 to 50 mum and optionally laminate a protective film onto the photocurable composition layer to obtain a dry film resist; whereby the photocurable r...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: OKA, HIDETAKA, TAYLOR, JAMES PHILIP, OHWA, MASAKI
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:The invention relates to a process for preparing a dry film resist by forming a photocurable resin composition onto a support film with a thickness of 1 to 50 mum and optionally laminate a protective film onto the photocurable composition layer to obtain a dry film resist; whereby the photocurable resin is formed from a homogeneous mixture comprising (a) from 20-90 wt% of an alkaline soluble binder oligomer or polymer; (b) from 5 to 60 wt% of one or more photopolymerizable monomers which are compatible with the oligomers and polymers of component (a); (c) from 0.01 to 20% by weight of one or more photoinitiators; (d) from 0 to 20% by weight of additives and/or assistants; and (e) from 0.1 to 10% by weight of a leuco triphenylmethane dye of the formula I, wherein R1 is a residue selected from, R2 is C1-C12 alkyl or phenyl which may be mono-, di- or tri-substituted by C1-C6 alkyl, trifluoromethyl, C1-6 alkoxy, C1-6 alkylthio, halogen and nitro; R3 is hydrogen or C1-C12 alkyl; R4 to R9 independently of one another are hydrogen or C1-C12 alkyl; X is O, S, NH or N-C1-C12-alkyl; (a) to (e) being 100% by weight. The above composition is useful to avoid unfavourable colour generation during the heat lamination.