Process for producing tertiary alcohol having adamantine skeleton

Process for producing tertiary alcohol having adamantine skeleton

This invention relates to a process for producing a tertiary alcohol having an adamantane skeleton which comprises reacting optionally substituted 2-adamantanone with a Grignard reagent in the presence of a rare earth halide. By the process in which optionally substituted 2-adamantanone is alkylated...

Ausführliche Beschreibung

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Bibliographische Detailangaben
1. Verfasser: YOSHITOME, TOSHIHIDE
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:This invention relates to a process for producing a tertiary alcohol having an adamantane skeleton which comprises reacting optionally substituted 2-adamantanone with a Grignard reagent in the presence of a rare earth halide. By the process in which optionally substituted 2-adamantanone is alkylated to produce a tertiary alcohol, the addition product can be efficiently produced in high yield while almost perfectly inhibiting the generation of reduction products.