Recycling of lead-free silver containing tin solder dross
This patent provides a recycling means for lead-free silver containing tin solder dross. In this patent, the dross was ground to a size of -50 mesh and subjected to a leaching condition of 4N HNO3, 70 DEG C, 2 hours and 5g/50ml to reach leaching recovery of 100% and 0.027% for Ag and Sn, respectivel...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | This patent provides a recycling means for lead-free silver containing tin solder dross. In this patent, the dross was ground to a size of -50 mesh and subjected to a leaching condition of 4N HNO3, 70 DEG C, 2 hours and 5g/50ml to reach leaching recovery of 100% and 0.027% for Ag and Sn, respectively. After filtration, the obtained solid is a salable high purity tin oxide. The pH of obtained leaching solution is adjusted to 2 by adding NH4 to precipitate all the Sn which contained in the solution. Then, 100% Ag which remained in the solution are precipitated by adding N2H4.H2O. The collected Ag containing precipitate was washed by 5M HCl in 70 DEG C for 15 minutes and by water in 27 DEG C for another 15 minutes. The washed precipitate was then melted at 1000 DEG C together with boric acid (H3BO3) to obtain a marketable silver ingot. |
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