Recycling of lead-free silver containing tin solder dross

This patent provides a recycling means for lead-free silver containing tin solder dross. In this patent, the dross was ground to a size of -50 mesh and subjected to a leaching condition of 4N HNO3, 70 DEG C, 2 hours and 5g/50ml to reach leaching recovery of 100% and 0.027% for Ag and Sn, respectivel...

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Bibliographische Detailangaben
Hauptverfasser: WANG, KUEN-SHENG, TSAI, SHANG-LIN, LEE, CHING-HWA, LIN, KAE-LONG, GUO, BI-FANG, CHEN, HEI-YI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:This patent provides a recycling means for lead-free silver containing tin solder dross. In this patent, the dross was ground to a size of -50 mesh and subjected to a leaching condition of 4N HNO3, 70 DEG C, 2 hours and 5g/50ml to reach leaching recovery of 100% and 0.027% for Ag and Sn, respectively. After filtration, the obtained solid is a salable high purity tin oxide. The pH of obtained leaching solution is adjusted to 2 by adding NH4 to precipitate all the Sn which contained in the solution. Then, 100% Ag which remained in the solution are precipitated by adding N2H4.H2O. The collected Ag containing precipitate was washed by 5M HCl in 70 DEG C for 15 minutes and by water in 27 DEG C for another 15 minutes. The washed precipitate was then melted at 1000 DEG C together with boric acid (H3BO3) to obtain a marketable silver ingot.