1-(TRIALKYLSTANNYLTHIOALKYL)-SILATRANES EXHIBITING BACTERISTATIC ACTIVITY AND METHOD OF THEIR SYNTHESIS

FIELD: organometallic compounds. SUBSTANCE: 1. Product: 1-(trialkylstannylthioalkyl)-silatranes of the general formula RSnS(CH)Si(OCHCH)N, where at R - ethyl n = 1 or 2; at R - butyl n = 1 exhibiting bacteriostatic activity. 2 . Method of synthesis of 1-(trialkylstannylthioalkyl)-silatranes of the g...

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Hauptverfasser:	Malkova T.I, Kuznetsova G.V, Kuznetsova Eh.Eh, Mirskov R.G, Voronkov M.G, Sorokin M.S
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY HUMAN NECESSITIES HYGIENE MEDICAL OR VETERINARY SCIENCE METALLURGY ORGANIC CHEMISTRY PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES
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Zusammenfassung:	FIELD: organometallic compounds. SUBSTANCE: 1. Product: 1-(trialkylstannylthioalkyl)-silatranes of the general formula RSnS(CH)Si(OCHCH)N, where at R - ethyl n = 1 or 2; at R - butyl n = 1 exhibiting bacteriostatic activity. 2 . Method of synthesis of 1-(trialkylstannylthioalkyl)-silatranes of the general formula RSNS(CH)Si(OCHCH)N, where at R - ethyl n = 1 or 2; at R - butyl n = 1. Trialkylmethoxystannane is interacted with silatrane-1-ylalkyl ether of thiocarboxylic or xanthic acid at 130-155 C. EFFECT: improved method of synthesis, bacteriostatic activity. 1. 1-(Триалкилстаннилтиоалкил)силатраны общей формулыRSS(CH)Si(OCHCH)Nгде при R - этил n=1 или 2;при R - бутил n=1;обладающие бактериостатической активностью.2. Способ получения 1-(триалкилстаннилтиоалкил)силатранов общей формулыRSS(CH)Si(OCHCH)N,где при R - этил n=1 или 2;при R - бутил n=1;заключающийся в том, что триалкилметоксистаннан подвергают взаимодействию с силатран-1-илалкиловым эфиром тиолкарбоновой или ксантогеновой кислоты при 130-155С.