METHOD OF OBTAINING ESTERS OF PHOSPHORUS ACIDS

A process for the preparation of a (thio)phosphoric(phosphonic) acid ester of the formula XY-R2 PARALLEL R1-P ANGLE R3R5 ¦¦ (I) Z---C-C-Hal ¦¦ R4R6 in which R1 is a straight-chain or branched alkyl, alkylmercapto or alkoxy group with up to 8 carbon atoms, R2 is alkyl with 1 to 8 carbon atoms optiona...

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Hauptverfasser: DITER ARLT,DT, KURT LEJ,DT
Format: Patent
Sprache:eng
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Zusammenfassung:A process for the preparation of a (thio)phosphoric(phosphonic) acid ester of the formula XY-R2 PARALLEL R1-P ANGLE R3R5 ¦¦ (I) Z---C-C-Hal ¦¦ R4R6 in which R1 is a straight-chain or branched alkyl, alkylmercapto or alkoxy group with up to 8 carbon atoms, R2 is alkyl with 1 to 8 carbon atoms optionally substituted by chlorine, R3, R4, R5 and R6 each independently is hydrogen or some other radical, X, Y and Z each independently is oxygen or sulfur, and Hal is chlorine or bromine, WHICH COMPRISES REACTING AN OLEFIN OF THE FORMULA R3R5 ANGLE C=C ANGLE (II) R4R6 in a one-step process with a halogenating agent and a (thio)phosphoric(phosphonic) acid ester of the formula XY-R2 PARALLEL R1-P ANGLE (III) Y-R2