METHOD OF PREPARING ACRYL NITRILE POLYMER OR COPOLYMER

The present invention relates to a process for the polymerization of acrylonitrile or a monomer mixture containing acrylonitrile as a main component and at least one other ethylenically unsaturated compound, characterized in that the polymerization is conducted at a temperature above 120 DEG C. unde...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: TOSIYUKI KOBASI,JA, NOBORU ABE,JA, MASAKHIKO OZAKI,JA, KENITI ONO,JA
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:The present invention relates to a process for the polymerization of acrylonitrile or a monomer mixture containing acrylonitrile as a main component and at least one other ethylenically unsaturated compound, characterized in that the polymerization is conducted at a temperature above 120 DEG C. under a pressure above the vapor pressure generated in the polymerization system under the polymerization conditions in a system in which water is present in a range of 3 to 50 percent by weight based on the total weight of the monomer(s) and water to produce an acrylonitrile polymer in a substantially molten state. The polymers produced according to the above process have the advantage of being able to be directly shaped by extrusion without the need of solvents.