PROCESS FOR THE PREPARATION OF ALKYLENE GLYCOLS

A process is disclosed for preparing an alkylene glycol by reacting an alkylene oxide with water in the presence of a catalyst comprising a polymeric organosiloxane ammonium salt having a silica-like skeleton and comprising units of the general formula (I) (I) wherein R1 to R4, Y and x are as specif...

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Bibliographische Detailangaben
1. Verfasser: VAN KRUCHTEN EUGENE M. G. A
Format: Patent
Sprache:eng
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Zusammenfassung:A process is disclosed for preparing an alkylene glycol by reacting an alkylene oxide with water in the presence of a catalyst comprising a polymeric organosiloxane ammonium salt having a silica-like skeleton and comprising units of the general formula (I) (I) wherein R1 to R4, Y and x are as specified in claim 1. Preferred are the catalysts wherein the anion Y is selected from the group of carboxylates having from 1-20 carbon atoms, hydrogen carbonate, hydrogen sulphite, hydrogen phosphate and metalate. These catalysts exhibit an enhanced selectivity stability.