METHOD FOR PRODUCING AMINES FROM OLEFINS ON SSZ-37 ZEOLITES

Discloses is a process for preparation of amines of general formula (I) wherein R1, R2, R3, R4, R5, R6 are hydrogen, C1-20 alkyl, C2-8 alkenyl, C2H propargyl, C3-12 cycloalkyl, C5-10 alkyl-cycloalkyl, C4-12 cycloalkyl-alkyl, aryl, C7-12 alkylaryl or C7-12 aralkyl, R1 and R2 together are saturated or...

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Hauptverfasser: KUMMER RUDOLF, STOPS PETER, ELLER KARSTEN
Format: Patent
Sprache:eng
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Zusammenfassung:Discloses is a process for preparation of amines of general formula (I) wherein R1, R2, R3, R4, R5, R6 are hydrogen, C1-20 alkyl, C2-8 alkenyl, C2H propargyl, C3-12 cycloalkyl, C5-10 alkyl-cycloalkyl, C4-12 cycloalkyl-alkyl, aryl, C7-12 alkylaryl or C7-12 aralkyl, R1 and R2 together are saturated or unsaturated C3-9 alkylene dichain and R3 or R5 are C21-200 alkenyl or together C2-12 alkylene dichain by the reaction of olefins of general formula (II) with ammonia or primary or secondary amines of general formula (III), under the temperature 200 to 350 C and the pressure 100 . 10exp(5) to 300 . 10exp(5) Pa in the presence of heterogeneous catalyst, using SSZ-37 zeolite as a heterogeneous catalyst.