Method for preparing hydroperoxides by oxygenation

Method for preparing hydroperoxides by oxygenation

Aryldialkylmethanes such as cumene are converted to the corresponding hydroperoxides by reaction with oxygen in the presence of a promoter which may be an alkali metal borate such as borax, an alkali metal salt of a polymer such as an acrylic polymer or an alkaline reagent in combination with a spec...

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Bibliographische Detailangaben
Hauptverfasser: FULMER JOHN WILLIAM, GOPINATHAN SARADA, SCHMIDHAUSER JOHN CHRISTOPHER, GOPINATHAN CHANGARAMPONNATH
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:Aryldialkylmethanes such as cumene are converted to the corresponding hydroperoxides by reaction with oxygen in the presence of a promoter which may be an alkali metal borate such as borax, an alkali metal salt of a polymer such as an acrylic polymer or an alkaline reagent in combination with a specific proportion of added water or water of hydration, also exemplified by borax. High yields of the hydroperoxide are obtained particularly when the promoter includes water.