EMULSIVE POLYMERISATE CONTAINING ACTIVATORS, METHOD FOR PRODUCTION THEREOF AND USE THEREOF IN TWO- OR MULTI-COMPONENT SYSTEMS

FIELD: chemistry.SUBSTANCE: described is a core-cladding emulsive polymerisate with an activator included in the core, which is obtained from polymerising a mixture containing: a) 5-99.9 wt % of one or more mono-functional (meth)acrylate monomers with water solubility of < 2 wt % at 20°C; b) 0-70 wt % of one or more monomers that copolymerisable with monomers a); c) 0-20 wt % of one or more compounds that are di- or multi-vinylenically unsaturated; d) 0-20 wt % of one or more polar monomers with water solubility of >2 wt % at 20°C, selected from (meth)acrylic acid and (meth)acrylamide, and c) 0.1-95 wt % of at least one activator. Wherein components a) to e) amount to 100 wt % of polymerisable components of the mixture, characterised by that e1) the activator is a compound of formula Iwhere Ris methyl; X is a linear alkanediiyl group with 1-18 carbon atoms; Rdenotes a hydrogen atom or a linear or branched alkyl residue with 1-12 carbon atoms; R, R, R, Rand Rindependently denote a hydrogen atom and that e2) the activator e) is covalently bonded to the emulsive polymerisate. Also described is a method of producing said emulsive polymerisate by "core-cladding" polymerisation in an aqueous emulsion, wherein components a) to e) at the first step are polymerised in form of a core, and then a mixture of components a) to d) are polymerised thereon as cladding in at least an additional step. Components a) to e) for the core and components a) to d) for the cladding are selected such that in the resultant polymerisate, the glass transition temperature of at least one cladding Tis higher than the glass transition temperature of the core T, wherein the glass transition temperature of at least one cladding Tis higher than 100°C, wherein the glass transition temperature Tis determined according to the EN ISO 11357 standard. Described is a two- or multi-component system with a controlled working life, which is curable at room temperature using a redox system of initiators containing A) 0.8-69.94 wt % emulsive polymerisate according to claims 1-7 or obtained by a method according to claim 8; B) 30-99.14 wt % of one or more ethylenically unsaturated monomers; C) 0.05-30 wt % peroxides; optionally D) 0-60 wt% unsaturated oligomers; E) 0.01-2 wt % polymerisation inhibitor; and optionally F) 0-800 pts.wt auxiliary substances and additives; wherein the sum of components A)+B)+C)+D)+E) is 100 wt %, and the amount of F) relates to 100 pts.wt of the sum A)+B)+C)+D)+E). Wherein com