ELECTROCHEMICAL METHOD OF FLUORALIPHATIC BIS-FLUORSULPHATE PRODUCTION ON ELECTROCATALITIC NANOMATERIALS

ELECTROCHEMICAL METHOD OF FLUORALIPHATIC BIS-FLUORSULPHATE PRODUCTION ON ELECTROCATALITIC NANOMATERIALS

FIELD: chemistry. ^ SUBSTANCE: controlled potential electrolysis of fluoro-olefins of general formula CF2=CF-Rf, where Rf=CF3, CF2OSO2F, R'FO, R'F = CF3, C2F5, C3F7 with anode representing nanoparticles applied on glass carbon is enabled diaphragmless cell equipped with anode and cathode i...

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Hauptverfasser: GRINBERG VITALIJ ARKAD'EVICH, PASYNSKIJ ALEKSANDR ANATOL'EVICH, TRUSOV LEV IL'ICH, KRAS'KO LJUDMILA BORISOVNA, STERLIN SERGEJ RAFAILOVICH, MAJOROVA NATALIJA ALEKSANDROVNA
Format: Patent
Sprache:eng ; rus
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Zusammenfassung:FIELD: chemistry. ^ SUBSTANCE: controlled potential electrolysis of fluoro-olefins of general formula CF2=CF-Rf, where Rf=CF3, CF2OSO2F, R'FO, R'F = CF3, C2F5, C3F7 with anode representing nanoparticles applied on glass carbon is enabled diaphragmless cell equipped with anode and cathode in fluosulphonic acid. It resulted in direct anodic oxidation of aforesaid fluoro-olefins. Herewith used anode is produced by thermolysis of organometallic platinum and iridium clusters on glass carbon substrate. ^ EFFECT: higher electrolysis efficiency. ^ 12 cl, 10 dwg, 4 tbl, 9 ex