METHOD OF PRODUCING P-TERPHENYL

FIELD: chemistry. ^ SUBSTANCE: present invention pertains to the method of producing p-terphenyl through alkylation of benzol using cyclohexanol in the presence of sulphuric acid, with subsequent dehydrogenation of the obtained p-dicyclohexylbenzol in a liquid phase at atmospheric pressure and 270-3...

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Hauptverfasser: KOSHEL' SERGEJ GEORGIEVICH, KUKUSHKINA NADEZHDA DMITRIEVNA, JUN'KOVA TAT'JANA ALEKSANDROVNA, SMIRNOVA ELENA VLADIMIROVNA, KOSHEL' GEORGIJ NIKOLAEVICH, LEBEDEVA NINA VALENTINOVNA, KUZNETSOVA ELENA ALEKSANDROVNA, KURGANOVA EKATERINA ANATOL'EVNA, POSTNOVA MARIJA VIKTOROVNA
Format: Patent
Sprache:eng ; rus
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Zusammenfassung:FIELD: chemistry. ^ SUBSTANCE: present invention pertains to the method of producing p-terphenyl through alkylation of benzol using cyclohexanol in the presence of sulphuric acid, with subsequent dehydrogenation of the obtained p-dicyclohexylbenzol in a liquid phase at atmospheric pressure and 270-320°C temperature on an aluminopalladium catalyst. The method is characterised by that, alkylation takes place with molar ratio of benzol, cyclohexanol and sulphuric acid 1;(3-5):(2-4) and 21-35°C temperature, with release of p-dicyclohexylbenzol. The p-dicyclohexylbenzol is re-crystallised before dehydrogenation. ^ EFFECT: use of this method speeds up the process, reduces energy expenditure and allows for obtaining a highly pure product. ^ 1 cl, 3 ex