METHOD OF OBTAINING 3,4-FULLERO [60]TETRAHYDROTHIOPHENE

FIELD: chemistry. ^ SUBSTANCE: claimed invention relates to field of organic chemistry, namely to method of obtaining 3,4-fullero(60)tetrahydrothiophene of formula (I) . Essence of method lies in interaction of fullerene C60 with dimethylsulfide in presence of catalyst Cp2TiCl2 in toluol medium at t...

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Hauptverfasser:	IBRAGIMOV ASKHAT GABDRAKHMANOVICH, KUNAKOVA RAJKHANA VALIULLOVNA, PUDAS MARKO, AKHMETOV ARSLAN RIFKHATOVICH, DZHEMILEV USEIN MEMETOVICH, TUKTAROV AJRAT RAMILEVICH
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	CHEMISTRY COMPOUNDS THEREOF HETEROCYCLIC COMPOUNDS INORGANIC CHEMISTRY METALLURGY NON-METALLIC ELEMENTS ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:	FIELD: chemistry. ^ SUBSTANCE: claimed invention relates to field of organic chemistry, namely to method of obtaining 3,4-fullero(60)tetrahydrothiophene of formula (I) . Essence of method lies in interaction of fullerene C60 with dimethylsulfide in presence of catalyst Cp2TiCl2 in toluol medium at temperature ~20°C during 66-78 hours. Target product output is 59-82%. ^ EFFECT: obtaining compound, which can be used as complex-forming agent, sorbent, biologically active compound, as well as in creation of novel materials with set electronic, magnetic and optical properties. ^ 1 tbl, 7 ex