METHOD FOR OBTAINING BUTADIENE POLYMERS AND BUTADIENE COPOLYMERS WITH STYRENE

FIELD: chemistry. ^ SUBSTANCE: invention claims method of obtaining polybutadiene or butadiene copolymers with styrene by polymerisation of respective monomers in hydrocarbon solvent medium in the presence of initiating system, where initiating system is a complex of lithium organic compound and mod...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	SILITRIN VALERIJ VASIL'EVICH, BOREJKO NATAL'JA PAVLOVNA, AKHMETOV IL'DAR GUMEROVICH, BUSYGIN VLADIMIR MIKHAJLOVICH, SAKHABUTDINOV ANAS GAPTYNUROVICH, BURGANOV TABRIZ GIL'MUTDINOVICH, KALASHNIKOVA OL'GA ALEKSANDROVNA, GIL'MUTDINOV NAIL' RAKHMATULLOVICH, GIL'MANOV KHAMIT KHAMISOVICH
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	FIELD: chemistry. ^ SUBSTANCE: invention claims method of obtaining polybutadiene or butadiene copolymers with styrene by polymerisation of respective monomers in hydrocarbon solvent medium in the presence of initiating system, where initiating system is a complex of lithium organic compound and modifying additive obtained by reaction of alkali metal lapramolate and tetrahydrofurfurylic alcohol, metal magnesium and sodium (potassium) at molar ratio of 1 : 2-4 : 1-2 : 0-2 respectively. Polybutadiene and butadiene copolymers with styrene with 1,2-link content in diene part adjustable from 9 to 75 wt %, reduced rate of macromolecules with mass over 106 g/mol (up to 5 wt %), is obtained at temperatures over 60C. ^ EFFECT: improved method of obtaining polybutadiene or butadiene copolymers with styrene. ^ 5 cl, 5 tbl, 14 ex