LONG-CHAIN ALKYLPHOSPHONIC ACIDS AS SOFT STEEL CORROSION INHIBITORS AND THEIR PRODUCTION

FIELD: chemistry. ^ SUBSTANCE: invention relates to phosphoroorganic chemistry, namely, to method of obtaining long-chain alkylphosphonic acids, possessing anticorrosion activity, based on alpha-olefins of industrial fraction C16-C18 and C20-C26. Invention can be applied for protection of pipelines,...

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Hauptverfasser: NIZAMOV IL'JAS SAIDOVICH, SERGEENKO GUL'NUR GATAULLOVNA, JARULLIN RAFINAT SAMATOVICH, AL'FONSOV VLADIMIR ALEKSEEVICH, GALIAKBEROV RASHID MUKHTAROVICH, MAGDEEV IL'DAR MUKHTAROVICH, ERMOLAEV EVGENIJ SERGEEVICH, BATYEVA EHL'VIRA SALIKHOVNA, KHODYREV JURIJ PAVLOVICH, SINJASHIN OLEG GEROL'DOVICH
Format: Patent
Sprache:eng ; rus
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Zusammenfassung:FIELD: chemistry. ^ SUBSTANCE: invention relates to phosphoroorganic chemistry, namely, to method of obtaining long-chain alkylphosphonic acids, possessing anticorrosion activity, based on alpha-olefins of industrial fraction C16-C18 and C20-C26. Invention can be applied for protection of pipelines, reservoirs, construction metallic structures, equipment for extraction, transportation and processing oil and gas, in metal processing. Long-chain alkylphosphonic acids are obtained by interaction of alpha-olefins of industrial fraction C16-C18 and C20-C26 with O,O-dimethylphosphorous acid in molar ratio 1:(1.0-2.0) in presence of benzoyl peroxide in amount of 1.0-5.0% of weight of dimethylphosphorous acid at 110-150°C during 10-12 hours in absence of solvent with further hydrolysis of intermediate higher O,O-dimethyl(alkyl) phosphonates with hydrochloric acid with heating, obtaining target product which represents mixture of long-chain alkylphosphonic acids. ^ EFFECT: elaboration of novel method of obtaining mixture of alkylphosphonic acids and soft steel corrosion inhibitor. ^ 2 cl, 1 tbl, 3 ex