RACEMIC-SELECTIVE OBTAINING, YIELDING ANSA-METALLOCENE BIPHENOXIDE COMPLEXES, WITH RELATIVELY SHORT ISOMERISATION TIME

RACEMIC-SELECTIVE OBTAINING, YIELDING ANSA-METALLOCENE BIPHENOXIDE COMPLEXES, WITH RELATIVELY SHORT ISOMERISATION TIME

FIELD: chemistry. ^ SUBSTANCE: invention pertains to the method of obtaining racemic metallocene bipheoxide complexes with formula I , where R1-R8 and R13-R17, M, Z have values given in the formula of invention of reaction of bridged complexes of transition metals with cyclopentadienyl derivatives o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: MJULLER PATRIK, DAMRAU KHANS-ROBERT-KHELL'MUT, TELL'E KRISTIAN, GARSIJA VALERI, SIDO KRISTIAN, LELON ZHAN-FRANSUA
Format: Patent
Sprache:eng ; rus
Schlagworte:
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:FIELD: chemistry. ^ SUBSTANCE: invention pertains to the method of obtaining racemic metallocene bipheoxide complexes with formula I , where R1-R8 and R13-R17, M, Z have values given in the formula of invention of reaction of bridged complexes of transition metals with cyclopentadienyl derivatives of alkaline metals or alkaline earth metals. The obtained reaction mixture is heated to temperature lying in the interval from -78 to 250°C, to the corresponding metallocene bipheoxide complexes. ^ EFFECT: possibility of use as a catalyst or components of catalyst for polymerisation of olefinic unsaturated compounds or as reagents or as catalysts in stereo-selective synthesis. ^ 5 cl, 7 ex