METHOD OF OBTAINING BRANCHED ALKANES

FIELD: organic synthesis. ^ SUBSTANCE: invention pertains to obtaining branched alkanes with general formula CnH2n+2, where n = 4-10. CCI4 is gradually added to a mixture of hexane, triethylaluminium - Et3Al and a catalyst - PdCl2, in an argon atmosphere at atmospheric pressure and temperature of 10...

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Hauptverfasser:	SALAMATINA TAT'JANA PETROVNA, SADYKOV RAIS ASKHATOVICH, SHAJBAKOVA MARIJA GENNAD'EVNA, DZHEMILEV USEIN MEMETOVICH, PETROV PAVEL NIKOLAEVICH
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL CHEMISTRY FIRELIGHTERS FUELS FUELS NOT OTHERWISE PROVIDED FOR LIQUEFIED PETROLEUM GAS LUBRICANTS METALLURGY NATURAL GAS ORGANIC CHEMISTRY PEAT PETROLEUM, GAS OR COKE INDUSTRIES SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K TECHNICAL GASES CONTAINING CARBON MONOXIDE
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Beschreibung
Zusammenfassung:	FIELD: organic synthesis. ^ SUBSTANCE: invention pertains to obtaining branched alkanes with general formula CnH2n+2, where n = 4-10. CCI4 is gradually added to a mixture of hexane, triethylaluminium - Et3Al and a catalyst - PdCl2, in an argon atmosphere at atmospheric pressure and temperature of 10-60°C for a period of 0.5-2 hours. The molar ratio of hexane: Et3Al : CCl4 : PdCl2 is 75:10:20:0.1. ^ EFFECT: obtaining of a mixture of branched alkanes with high output. ^ 1 tbl, 1 ex