METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE

METHOD FOR PREPARING 1-(N,N-DIPROP-2-ENYLAMINO)-1,2-DIHYDRO[60]FULLERENE

FIELD: organic chemistry, chelating agents, chemical technology. ^ SUBSTANCE: invention relates to a method for synthesis of 1-(N,N-diprop-2-enylamino)-1,2-dihydro[60]fullerene of the formula (1): . Method involves interaction of fullerene-C60 with N,N-diallylamine [(CH2=CHCH2)NH] in the mole ratio...

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Hauptverfasser: SALAMATINA TAT'JANA PETROVNA, DZHAMILEV USEIN MEMETOVICH, IBRAGIMOV ASKHAT GABDRAKHMANOVICH, PUDAS MARKO, TUKTAROV AJRAT RAMILEVICH
Format: Patent
Sprache:eng ; rus
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
ORGANIC CHEMISTRY
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Zusammenfassung:FIELD: organic chemistry, chelating agents, chemical technology. ^ SUBSTANCE: invention relates to a method for synthesis of 1-(N,N-diprop-2-enylamino)-1,2-dihydro[60]fullerene of the formula (1): . Method involves interaction of fullerene-C60 with N,N-diallylamine [(CH2=CHCH2)NH] in the mole ratio fullerene-C60 : N,N-diallylamine = 0.01:(0.01-0.011) in the presence of titanocene dichloride Cp2TiCl2 as a catalyst taken in the amount 15-25 mol.% with respect to fullerene-C60 in toluene medium, at room temperature for 18-30 h. The yield of the end product is 68-90%. Synthesized compound can be used as chelating agents, sorbents and biologically active compounds, and in creature of novel materials with desired electronic, magnetic and optical properties. ^ EFFECT: improved method of synthesis. ^ 1 tbl, 1 ex