1,2,3-TRIS[(AMMONIA)METHYLCARBONYLOXYPOLY(ALKLYLENEOXY)]-PROPANE TRICHLORIDES HAVING BACTERICIDAL AND FUNGICIDAL ACTIVITY AND METHOD FOR PRODUCTION THEREOF

FIELD: organic chemistry. ^ SUBSTANCE: invention relates to compounds of general formula , wherein: when R1=R2=H R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 49, b+d+f = 9; when R1=R2=H R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 55, b+d+f = 10; when R1=R2=H R3= C16H33, a+c+e = 49, b+d+f...

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Hauptverfasser: RAVILOV ABDULKHAMIT ZARIPOVICH, ROMANOV GENNADIJ VASIL'EVICH, NURIEV IL'DAR MUKHAMATNUROVICH, JUSUPOVA GALIJA RASYKHOVNA, IVANOV ARKADIJ VASIL'EVICH, CHULKOV ALEKSEJ KONSTANTINOVICH, SHISHKO ALEKSEJ AL'FREDOVICH, KAMALOV BULAT VAGIZOVICH, SAVRILOV MARSEL' ROBINZONOVICH, FAKHRETDINOV PAVEL SAGITOVICH, UGRJUMOVA VALENTINA STEPANOVNA
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Sprache:eng ; rus
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Zusammenfassung:FIELD: organic chemistry. ^ SUBSTANCE: invention relates to compounds of general formula , wherein: when R1=R2=H R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 49, b+d+f = 9; when R1=R2=H R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 55, b+d+f = 10; when R1=R2=H R3= C16H33, a+c+e = 49, b+d+f = 9; when R1=R2=H R3= C16H33, a+c+e = 55, b+d+f = 10; when R1=R2=CH3 R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 49, b+d+f = 9; when R1=R2=CH3 R3=aliphatic C10-C16-hydrocarbon radical, a+c+e = 55, b+d+f = 10; when R1=R2=H R3=aliphatic C17-C20-hydrocarbon radical, a+c+e = 66, b+d+f = 15; when R1=R2=H R3=aliphatic C17-C20-hydrocarbon radical, a+c+e = 76, b+d+f = 18. Also disclosed is method for production of abovementioned compounds by interaction of 1,2,3-tris[hydroxypoly(alkyleneoxy)]-propanes with monochloroacetic acid in presence of acetic catalyst in medium of boiling organic solvent with azeotropic removing of formed water followed by treatment at heating of obtained product in polar solvent medium with amine compounds of formula R1R2R3N, wherein R1=R2=H, CH3; R3=C16H33, aliphatic C10-C16- or C17-C20-hydrocarbon radical, in molar ratio of hydroxy propane derivatives:monochloroacetic acid:amine compound = 1.0:3.0-3.2:3.0-3.2, respectively. ^ EFFECT: new compounds with bactericidal and fungicidal activity. ^ 7 cl, 2 tbl, 7 ex