NOVEL STRONG ACIDS, METHOD FOR THEIR PREPARING, THEIR SOLUTION, SALT AND METHOD FOR PREPARING SALT

FIELD: chemistry of organophosphorus compounds, chemical technology. ^ SUBSTANCE: invention relates to fluorinated phosphoric acids of the general formula: [RyPF6-y]-H+ [I] wherein y = 1, 2 or 3; ligands R are similar and R represents perfluorinated (C1-C8)-alkyl or aryl group or partially fluorinat...

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Hauptverfasser:	SHMIDT MIKHAEHL, KUCHERINA ANDRIJ, VILL'NER KHEL'GE, IGNAT'EV NIKOLAJ, SARTORI PETER, KHAJDER UDO, KJUNER ANDREAS, KHILARIUS FOL'KER
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM APPARATUS THEREFOR BASIC ELECTRIC ELEMENTS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY ELECTRICITY ELECTROLYTIC OR ELECTROPHORETIC PROCESSES ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	FIELD: chemistry of organophosphorus compounds, chemical technology. ^ SUBSTANCE: invention relates to fluorinated phosphoric acids of the general formula: [RyPF6-y]-H+ [I] wherein y = 1, 2 or 3; ligands R are similar and R represents perfluorinated (C1-C8)-alkyl or aryl group or partially fluorinated (C1-C8)-alkyl or aryl group wherein some atoms F and H can be replaced for chlorine atom. Also, invention relates to a method for synthesis of above described acids by interaction perfluoroalkylphosphorane with fluorohydrogen in the presence of suitable solvent and/or proton acceptor, to salts comprising cation and anion of above described acid, and to a method for synthesis of salts. Acids of the formula [I] can be easily synthesized and show high proton activity and stable at room temperature in highly concentrated solution. ^ EFFECT: improved method of synthesis, improved and valuable properties of acids. ^ 18 cl, 33 ex