ABSTRACT

FIELD: ION-EXCHANGE MATERIALS. ^ SUBSTANCE: invention relates to a process of preparing gel-like cationites for use in treatment and purification processes. Gel-like cationites are prepared by inoculating-incoming process wherein (a) aqueous suspension of microcapsulated cross-linked styrene polymer...

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Bibliographische Detailangaben
Hauptverfasser: ZAJDEL' RJUDIGER, BORN RAL'F-JURGEN, KHALLE OLAF, SHMID KLAUDIA, KLIPPER RAJNKHOL'D, PODSTSUN VOL'FGANG, SHNEGG UL'RIKH
Format: Patent
Sprache:eng ; rus
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Beschreibung
Zusammenfassung:FIELD: ION-EXCHANGE MATERIALS. ^ SUBSTANCE: invention relates to a process of preparing gel-like cationites for use in treatment and purification processes. Gel-like cationites are prepared by inoculating-incoming process wherein (a) aqueous suspension of microcapsulated cross-linked styrene polymer in the form of granules and containing cross-linking agent is provided as inoculating polymer; (b) inoculating polymer is left to swell in monomer mixture composed of vinyl monomer, cross-linking agent, and radical initiator, namely peracid aliphatic ester; (c) monomer mixture is polymerized in inoculating polymer; and (d)resulting copolymer is functionalized via sulfatization. Process is characterized by that, in step (a), content of cross-linking agent in cross-linked styrene copolymer amounts to 3.5-7 wt % and inoculum-to-income ratio in step (b) amounts to 1:(0.25-1.5). ^ EFFECT: enabled preparation of gel-like cationites having high osmotic and mechanic stabilities as well as improved oxidation resistance. ^ 7 cl, 9 tbl, 9 ex