1,2,3-TRIS-[(AMMONIO)METHYLCARBONYLOXYPOLY(ALKYLENEOXY)]-PROPANE TRICHLORIDES POSSESSING PROPERTY OF EMULGATORS OF AQUEOUS-MAZUT EMULSION AND METHOD FOR THEIR PREPARING

FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention relates to novel 1,2,3-tris-[(ammonio)methylcarbonyloxypoly(alkyleneoxy)]propane trichlorides of the formula: wherein: if R1 = R2 = R3 mean -CH2CH2OH then a + c + e (the total degree of oxypropylation) = 49, b + d + f (the total d...

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Hauptverfasser:	ROMANOV GENNADIJ VASIL'EVICH, NURIEV IL'DAR MUKHAMATNUROVICH, FAKHRETDINOV PAVEL SAGITOVICH
Format:	Patent
Sprache:	eng ; rus
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MIXING, e.g. DISSOLVING, EMULSIFYING, DISPERSING ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING
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Zusammenfassung:	FIELD: organic chemistry, chemical technology. ^ SUBSTANCE: invention relates to novel 1,2,3-tris-[(ammonio)methylcarbonyloxypoly(alkyleneoxy)]propane trichlorides of the formula: wherein: if R1 = R2 = R3 mean -CH2CH2OH then a + c + e (the total degree of oxypropylation) = 49, b + d + f (the total degree of oxyethylation) = 9; if R1 = R2 = R3 mean -CH2CH2OH then a + c + e = 55, b + d + f = 10; if R1 = R2 = R3 mean -CH2CH2OH then a + c + e = 66, b + d + f = 15; if R1 = R = R3 -CH2CH2OH then a + c + e = 76, b + d + f = 18; if R1 = R2 mean hydrogen atom (H); R3 means aliphatic hydrocarbon radical comprising 10-16 carbon atoms then a + c + e = 76, b + d + f =18; if R1 = R2 mean H; R3 means aliphatic hydrocarbon radical comprising 17-20 carbon atoms then a + c + e = 49, b + d + f = 0; if R1 = R2 mean H; R3 means aliphatic hydrocarbon radical comprising 17-20 carbon atoms then a + c + e = 55, b + d + f = 0; if R = R means H; R3 means then a + c + e = 49, b + d + f = 9; if R1 = R2 mean H; R3 means then a + c + e = 55, b + d + f =10, and to a method for their synthesis. Method involves interaction 1,2,3-tris-[hydroxypoly(alkyleneoxy)propanes of the formula: wherein a + c + e = 49-76, b + d + f = 0-18 with monochloroacetic acid in the presence of acidic catalyst, in boiling organic solvent medium and azeotropic removal of formed water and the following treatment of the synthesized reaction product at heating with amino-compounds of the formula: R1R2N wherein R1 = R2 mean -H, -CH2CH2OH; R3 means -CH2CH2OH, aliphatic radical comprising 10-16 or 17-20 carbon atoms, and in the molar ratio of reagents - propane hydroxyl derivatives : monochloroacetic acid : amino-compounds = 1:(3.0-3.2):(3.0-3.2), respectively. Novel compounds possess properties of emulsifiers of aqueous-mazut emulsions. ^ EFFECT: improved method of synthesis, valuable technical properties of compounds. ^ 6 cl, 1 tbl, 10 ex