CATALYST INCLUDING VIII SECONDARY GROUP METAL COMPLEX BASED ON ONE OF BIDENTATE PHOSPHONITE LIGANDS, AND PHOSPHONITE LIGAND
FIELD: organic synthesis catalysts. SUBSTANCE: invention relates to production of catalysts for synthesis of adiponitrile and describes catalyst comprising at least one complex of VIII secondary group c with at least one bidentate phosphonite ligand of general formula I (represented in description)...
Gespeichert in:
Hauptverfasser: | , , , |
---|---|
Format: | Patent |
Sprache: | eng ; rus |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | FIELD: organic synthesis catalysts. SUBSTANCE: invention relates to production of catalysts for synthesis of adiponitrile and describes catalyst comprising at least one complex of VIII secondary group c with at least one bidentate phosphonite ligand of general formula I (represented in description) or their salts and mixtures. Described are also production of mixtures of monoolefin mononitriles with 5 carbon atoms, catalytic isomerization of branched aliphatic monoalkennitriles, and production of adiponitrile. EFFECT: increased selectivity and catalytic activity in hydrocyanation of 1,3- butadiene and hydrocarbon mixtures. 8 cl, 3 tbl, 4 ex |
---|