METHOD OF PRODUCTION OF CHLORINE DERIVATIVES OF FULLERENE C60

chemical industry; organic synthesis. SUBSTANCE: compound ferrous or ferric iron is placed in ampoule, for example, C60, FeBr2, ferric acetate (II), ferric acetyl acetonate (III), ferric palmitate (III), ferric stearate (III) salt (III) and naphthene acid salt, ferric ethyl hexanate (III); chlorofor...

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Bibliographische Detailangaben
Hauptverfasser:	LATYPOV V.N, KHUSNUTDINOV R.I, MUSLIMOV Z.S, DZHEMILEV U.M
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMISTRY COMPOUNDS THEREOF INORGANIC CHEMISTRY METALLURGY NON-METALLIC ELEMENTS
Online-Zugang:	Volltext bestellen
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Beschreibung
Zusammenfassung:	chemical industry; organic synthesis. SUBSTANCE: compound ferrous or ferric iron is placed in ampoule, for example, C60, FeBr2, ferric acetate (II), ferric acetyl acetonate (III), ferric palmitate (III), ferric stearate (III) salt (III) and naphthene acid salt, ferric ethyl hexanate (III); chloroform or methylene chloride, fullerene FeCl3, C60, powder-like titanium. Molar ratio Fe:Ti is 1:1. Ferro-titanium catl\alyst may additionally contain polymer, for example, polybutadiene or polyisoprene. Molar ratio Fe: Ti: polymer = 1: 1 (1-10). Molar ratio of catalyst and fullerene is 1(100-500). Reaction is performed at 100-200 C for 5 to 20 h. Output of fullerene chlorine derivatives is 65 to 83%. Chlorine derivatives C60 contain 1 to 6 atoms of chlorine. EFFECT: enhanced efficiency. 1 ex, 1 tbl