MIXED PLASTICIZER AND METHOD OF PREPARATION THEREOF

organic chemistry. SUBSTANCE: described is mixed polymer plasticizer of N, N'-dialkylmethylene dinitramines, namely compound of general formula I: RNNO2CH2NNO2R (I) wherein R is CH3, C2H5 or CH2CH2ONO2, compound of general formula: RNNO2CH2NNO2R' (II) wherein R is as defined above, and R&#...

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Hauptverfasser: TERNIKOVA T.V, SERKOV S.A, ERMAKOV A.S, VARFOLOMEEVA O.N, LUK'JANOV O.A, SIGAJ N.V, TARTAKOVSKIJ V.A, VINOGRADOV D.B
Format: Patent
Sprache:eng ; rus
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Zusammenfassung:organic chemistry. SUBSTANCE: described is mixed polymer plasticizer of N, N'-dialkylmethylene dinitramines, namely compound of general formula I: RNNO2CH2NNO2R (I) wherein R is CH3, C2H5 or CH2CH2ONO2, compound of general formula: RNNO2CH2NNO2R' (II) wherein R is as defined above, and R' is CH2CH2ONO2, (CH2)3ONO2 or CH2CH(ONO2)CH3, compound of general formula: R'NNO2CH2NNO2R' (III) wherein R' is as defined above, ratios of components being as follows, wt %: I, 3-7.6; II, 20-52; and III, the balance. Plasticizer is prepared by reacting mixture of two N-alkylsulfamates of general formula: R''NHSO3M wherein R'' is CH3, C2H5 or CH2CH2OH and general formula: R'''NHSO3M wherein R''' is CH2CH2OH and general formula R'''NHSO3M wherein R''' is with formaldehyde at molar ratio of 7: 1-1: 7, respectively and subsequently nitrating reaction product with mixture of nitric and sulfuric at lower temperature. The resulting plasticizer has higher content of active oxygen and has high plasticizing power to nitrocellulose. EFFECT: improved properties of the mixed plasticizer. 3 cl, 1 ex, 1 tbl