INDUSTRIAL CHLORAL PRODUCTION PROCESS

INDUSTRIAL CHLORAL PRODUCTION PROCESS

industrial organic synthesis. SUBSTANCE: process comprises stepped countercurrent chlorination of ethanol with elementary chlorine. High-density raw material is fed into the first chlorination step and gases released in this step are used to treat lower-density reaction mixture in the next step. Chl...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: VYRAZHEJKIN E.S, TALAGAEVA I.A, GOLUBEV A.N, SHABALIN D.A, NASONOV JU.B, ZAKHAROV V.JU, DENISOV A.K, ABRAMOV O.B, DEDOV A.S, MASLJAKOV A.I, TATAUROV V.L, BEL'TJUGOVA O.N
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:industrial organic synthesis. SUBSTANCE: process comprises stepped countercurrent chlorination of ethanol with elementary chlorine. High-density raw material is fed into the first chlorination step and gases released in this step are used to treat lower-density reaction mixture in the next step. Chlorination is carried out in presence of 28-76-% aqueous solution of di- and trichloroacetic acids, proportion of this solution in reaction mixture being 18 to 50%. Chloral is withdrawn from reaction zone with releasing gases, from which the former is separated by condensation. EFFECT: increased degree of ethanol conversion and lowered level of ethanol and its derivatives in product. 5 cl, 1 tbl, 5 ex