METALLOCENES, CATALYTIC SYSTEM CONTAINING THEREOF, METHOD OF PREPARING POLYOLEFINS, POLYOLEFIN

FIELD: organometallic synthesis. SUBSTANCE: invention provides new metallocene compounds depicted by general formula I: , in which M2 is IV group metal; R1 and R2 are halogen atoms; R3 hydrogen atom; R4 hydrogen, aryl, or two or more R4 residues together with atoms linked to them form cyclic system;...

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Hauptverfasser: KRISTIAN KOL'PAINTNER, ROBERT KLAJN, ANDREAS VINTER, KLAUS KJULAJN, MIKHAEL' AUL'BAKH, BERND BAKHMANN, FRANK KJUBER, VAL'TER SHPALEK
Format: Patent
Sprache:eng
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Zusammenfassung:FIELD: organometallic synthesis. SUBSTANCE: invention provides new metallocene compounds depicted by general formula I: , in which M2 is IV group metal; R1 and R2 are halogen atoms; R3 hydrogen atom; R4 hydrogen, aryl, or two or more R4 residues together with atoms linked to them form cyclic system; R5 lower alkyl; R6 hydrogen, lower alkyl; R7 is group or wherein R11 and R12 are lower alkyls; provided that, at least one of R6 residues and also at least one of R4 and R5 residues differ from hydrogen atom. EFFECT: enlarged choice of organometallic catalysts. 9 cl, 27 ex