LOW-NOISE POTENTIOSTAT FOR AMPEROMETRIC MEASUREMENTS IN MAGNETICALLY STIRRED SOLUTIONS
The invention relates to a low-noise potentiostat meant to be used for amperometric analyses in magnetically stirred solutions, using an electrochemical cell with three electrodes: an indicating electrode (WE), a reference electrode (RE) and an auxiliary electrode (CE). According to the invention, t...
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Zusammenfassung: | The invention relates to a low-noise potentiostat meant to be used for amperometric analyses in magnetically stirred solutions, using an electrochemical cell with three electrodes: an indicating electrode (WE), a reference electrode (RE) and an auxiliary electrode (CE). According to the invention, the potentiostat comprises an analogue circuit consisting of an operational circuit (OA) in a repeater mounting, with the role of taking over the steady voltage V, an operational circuit (OA) in amplifier mounting with negative reaction, with the role of providing a current Ineeded by the electrochemical cell and an operational circuit (OA) in a repeater mounting, with the role of applying the voltage Vto the cell with three electrodes, as well as a circuit processing the signal I, consisting of an instrumentation amplifier (INA) in trans-impedance mounting, the output voltage of which linearly depends on the cell signal and has a value sufficiently high for it to be read by an analogue-digital processing circuit of microcontroller type.
Invenţia se referă la un potenţiostat de zgomot redus, destinat spre a fi folosit pentru analize amperometrice în soluţii agitate magnetic, folosind o celulă electrochimică având trei electrozi: un electrod (WE) indicator, un electrod (RE) de referinţă şi un electrod (CE) auxiliar. Potenţiostatul conform invenţiei cuprinde un circuit analogic, format dintr-un circuit operaţional (OA) în montură de repetor, cu rolul de a prelua tensiunea fixă V, dintr-un circuit operaţional (OA) în montură de amplificator cu reacţie negativă, cu rolul de a furniza un curent Icerut de celula electrochimică, şi dintr-un circuit operaţional (OA) în montură de repetor, cu rolul de a aplica tensiunea Vpe celula cu trei electrozi, precum şi un circuit de prelucrare a semnalului I, format dintr-un amplificator de instrumentaţie (INA) în montură de transimpedanţă, a cărui tensiune de ieşire depinde liniar de semnalul celulei, şi are o valoare suficient de mare pentru a fi citită de un circuit de prelucrare analog-digitală de tip microcontroler. |
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