Acetic acid recovery system used for the iodide-promoted rhodium catalysed carbonylation of methanol to acetic acid

A process for reduction and/or removal of permanganate reducing compounds (PRC's) and C2-12alkyl iodide compounds formed in the carbonylation of methanol to a product of acetic acid, wherein said methanol is carbonylated in a suitable liquid phase reaction medium comprising a Group VIII metal catalyst, an organic iodide and iodide salt catalyst promoter; the products of carbonylation are separated into a volatile phase comprising product, and a less volatile phase comprising Group VIII metal catalyst, acetic acid, and iodide catalyst promoter; the product phase distilled in a distillation tower to yield a purified product and an overhead comprising organic iodide, methyl acetate, water, acetic acid, and unreacted methanol, directing at least a portion of the overhead to an overhead receiver decanter which separates the overhead into a light phase, comprising acetic acid and water, and a heavy phase comprising methyl acetate and organic iodide; and recycling the heavy phase to the carbonylation reactor, comprising the steps of: (a) Directing the light phase comprising acetic acid and water to a distiller which separates the mixture into two streams: residue stream comprising water and acetic acid and overhead stream comprising methyl iodide, methyl acetate, methanol, C2-12alkyl iodides, and PRC's; (b) Circulating the residue stream of step (a) to a heat exchanger and ultimately back to the reactor, and the overhead stream of step (a) to a second distiller which serves to strip the PRC's from the mixture. (c) Optionally forwarding the overhead stream containing PRC's of step (b) to an extractor to remove organic iodide compounds thereform; and, (d) Separating out concentrated PRC's for disposal and returning the organic iodide phase of (b) or (c) as a stream containing a lower percentage of PRC's and C2-12alkyl iodides to the carbonylation reactor. Figure 1 illustrates the removal of carbonyl impurities from the intermediate stream of the carbonylation process. Stream 28, comprising PRC's is directed to an overhead receiver decanter 16 where the light ends phase, stream 30, is directed to distillation column 18. The first vapour phase acetic acid stream (28) comprises methyl iodide, methyl acetate, acetaldehyde and other carbonyl components. This stream is then condensed and separated (in vessel 16) to form a first vapour phase stream to separate the heavy phase product containing the larger proportion of catalytic components - which is re-circulated to the