Tverrbindbare polymerer, fremgangsmate for produksjon derav, og formlegemer dannet av tverrbindbare polymerer

The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is...

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Bibliographische Detailangaben
Hauptverfasser:	HORN MICHAEL, MACK HELMUT, JENKER PETER, STANDKE BURKHARD, EDELMANN ROLAND, FRINGS ALBERT-JOHANNES, LAVEN RALF, MONKIEWICZ JAROSLAW
Format:	Patent
Sprache:	nor
Schlagworte:	AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G BASIC ELECTRIC ELEMENTS CABLES CHEMISTRY COMPOSITIONS BASED THEREON CONDUCTORS ELECTRICITY GENERAL PROCESSES OF COMPOUNDING INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS INSULATORS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MAKING GRANULES OR PREFORMS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PREPARATION OR PRETREATMENT OF THE MATERIAL TO BESHAPED RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIALCONTAINING PLASTICS SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING ORDIELECTRIC PROPERTIES THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL WORKING-UP
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Beschreibung
Zusammenfassung:	The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is carried out in the presence of(a) an alkylsilane of the formula I, whereR1 is a monovalent hydrocarbon radical having from 1 to 33 carbon atoms or a divalent hydrocarbon radical having from 4 to 24 carbon atoms,R2 is a hydrocarbon radical having from 1 to 10 carbon atoms,X are identical or different hydrolyzable radicals,n is 0, 1 or 2 andm is 1 or 2 and/or(b) a fluoroalkylsilane of the formula whereR3 is a fluoroalkyl radical,R4 is an alkyl radical andX is a hydrolyzable radical,x is an integer from 1 to 3,y is 0, 1 or 2 andz is an integer from 1 to 3, with the proviso that the sum x+y+z=4.