PROCESS FOR THE PREPARATION OF A CATALYST FOR OLEFIN POLYMERIZATION

IMPROVEMENTS OR MODIFICATIONS OF EARLIER PROCESS FOR PREPARING CHROMIUM-CONTAINING COMPOUNDS, SUCH AS, FOR EXAMPLE, CHROMIUM PYRROLIDES, BY FORMING A MIXTURE OF A CHROMIUM SALT, A METAL AMIDE, PARTICULARLY A PYRROLIDE, AND AN ELECTRON PAIR DONOR SOLVENT, SUCH AS, FOR EXAMPLE, AN ETHER, AND REACTION...

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Bibliographische Detailangaben
Hauptverfasser:	WILLIAM KEVIN REAGEN, TED MATTHEW PETTIJOHN, JEFFREY WILLIS FREEMAN, BRIAN KEITH CONROY, ELIZABETH ANN BENHAM
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	IMPROVEMENTS OR MODIFICATIONS OF EARLIER PROCESS FOR PREPARING CHROMIUM-CONTAINING COMPOUNDS, SUCH AS, FOR EXAMPLE, CHROMIUM PYRROLIDES, BY FORMING A MIXTURE OF A CHROMIUM SALT, A METAL AMIDE, PARTICULARLY A PYRROLIDE, AND AN ELECTRON PAIR DONOR SOLVENT, SUCH AS, FOR EXAMPLE, AN ETHER, AND REACTION WITH AN UNSATURATED HYDROCARBON ARE DISCLOSED, INCLUDING USE OF PYRROLE OR DERIVATIVES THEREOF AS THE PYRROLIDE AND AN ALIPHATIC AS THE UNSATURATED HYDROCARBON. A NEW PROCESS FOR PREPARING A CATALYST SYSTEM COMPRISES COMBINING A METAL SOURCE, A PYRROLE-CONTAINING COMPOUND AND A METAL ALKYL WITHOUT A PRELIMINARY REACTION STEP BETWEEN THE METAL SOURCE AND THE PYRROLE-CONTAINING COMPOUND IN THE PRESENCE OF AN ELECTRON DONOR SOLVENT. THESE CATALYST SYSTEM AND CHROMIUM-CONTAINING COMPOUNDS EITHER UNSUPPORTED OR SUPPORTED ON AN INORGANIC OXIDE SUPPORT, IF DESIRED FUNCTIONING AS A COCATALYST IN COMBINATION WITH ANOTHER POLYMERIZATION CATALYST, SUCH AS CONTAINING CHROMIUM OR TITANIUM, CAN BE USED TO TRIMERIZE, OLIGOMERIZE, AND/OR POLYMERIZE OLEFINS.