FATTY AMINES, AMIDOAMINES, AND THEIR DERIVATIVES FROM NATURAL OIL METATHESIS

Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their es...

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Hauptverfasser: MURPHY, Dennis S, SKELTON, Patti, WIESTER, Michael, LUEBKE, Gary, BROWN, Aaron, WOLFE, Patrick Shane, BERNHARDT, Randal J, WHITLOCK, Laura Lee, ALLEN, Dave R, ALONSO, Marcos, MUNIE, Lawrence A, SHAPIRO, Irene, BUCHEK, Kelly, MASTERS, Ronald A, LUKA, Renee, MALEC, Andrew D, SOOK, Brian, TERRY, Michael R
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Sprache:eng ; spa
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Zusammenfassung:Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. Se describen composiciones de amina grasa formadas de un ácido monoinsaturado de C10-C17 derivado de metátesis, el ácido octadeceno-1,18-dióico, o sus derivados de éster; en otro aspecto, se. describen amidoaminas grasas formadas al reaccionar un ácido monoinsaturado de C10-C17 derivado de metátesis, el ácido octadeceno1,18-diáico, o sus derivados de éster con una amina terciaria sustituida con aminoalquilo; las aminas o amidoaminas grasas son ventajosamente sulfonadas, sulfatadas, oxidadas, o reducidas; en otros aspectos, el derivado de éster es un triglicérido modificado formado por auto-metátesis de un aceite natural o un triglicérido insaturado formado por metátesis cruzada de un aceite natural con una olefina.