MANUFACTURING METHOD OF POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE AND LITHIUM SECONDARY-BATTERY COMPRISING THE SAME

The present invention aims to provide a positive electrode active material with excellent initial capacity and initial efficiency characteristics and provides a manufacturing method of a positive electrode active material, a positive electrode active material manufactured thereby, and a positive ele...

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Hauptverfasser: CHEONG SANG HUN, NAM JAE KEUN, KIM DONG HWAN, OH MYOUNG HWAN
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creator CHEONG SANG HUN
NAM JAE KEUN
KIM DONG HWAN
OH MYOUNG HWAN
description The present invention aims to provide a positive electrode active material with excellent initial capacity and initial efficiency characteristics and provides a manufacturing method of a positive electrode active material, a positive electrode active material manufactured thereby, and a positive electrode and a lithium secondary battery comprising the same, wherein the manufacturing method of a positive electrode active material comprises: a step (A) of mixing a positive electrode active material precursor with a lithium-containing raw material to manufacture a mixture and firing the mixture to manufacture a fired product; and a step (B) of washing the fired product with a cleaning solution and drying the same to manufacture a lithium transition metal oxide. The firing is performed under an oxygen atmosphere of 90 volume% of oxygen concentrations. From a time when 55 - 85 % of the entire firing time goes by, the firing is performed under an oxygen atmosphere of 20-60 volume% of oxygen concentrations. 본 발명은 초기 용량 및 초기 효율 특성이 우수한 양극 활물질을 제공하기 위한 것으로, (A) 양극 활물질 전구체와 리튬 함유 원료 물질을 혼합하여 혼합물을 제조하고, 상기 혼합물을 소성하여 소성품을 제조하는 단계; 및 (B) 상기 소성품을 수세 용액으로 수세한 후, 건조하여 리튬 전이금속 산화물을 제조하는 단계;를 포함하고, 상기 소성은 산소 농도가 90부피% 이상인 산소 분위기 하에서 수행하다가, 전체 소성 시간의 55% 내지 85%가 경과한 시점부터 산소 농도가 20부피% 내지 60부피%인 산소 분위기 하에서 수행하는 것인 양극 활물질의 제조 방법, 이러한 방법에 의해 제조된 양극 활물질, 이를 포함하는 양극 및 리튬 이차전지를 제공한다.
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The firing is performed under an oxygen atmosphere of 90 volume% of oxygen concentrations. From a time when 55 - 85 % of the entire firing time goes by, the firing is performed under an oxygen atmosphere of 20-60 volume% of oxygen concentrations. 본 발명은 초기 용량 및 초기 효율 특성이 우수한 양극 활물질을 제공하기 위한 것으로, (A) 양극 활물질 전구체와 리튬 함유 원료 물질을 혼합하여 혼합물을 제조하고, 상기 혼합물을 소성하여 소성품을 제조하는 단계; 및 (B) 상기 소성품을 수세 용액으로 수세한 후, 건조하여 리튬 전이금속 산화물을 제조하는 단계;를 포함하고, 상기 소성은 산소 농도가 90부피% 이상인 산소 분위기 하에서 수행하다가, 전체 소성 시간의 55% 내지 85%가 경과한 시점부터 산소 농도가 20부피% 내지 60부피%인 산소 분위기 하에서 수행하는 것인 양극 활물질의 제조 방법, 이러한 방법에 의해 제조된 양극 활물질, 이를 포함하는 양극 및 리튬 이차전지를 제공한다.</abstract><oa>free_for_read</oa></addata></record>
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subjects BASIC ELECTRIC ELEMENTS
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
ELECTRICITY
INORGANIC CHEMISTRY
METALLURGY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title MANUFACTURING METHOD OF POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE AND LITHIUM SECONDARY-BATTERY COMPRISING THE SAME
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