MANUFACTURING METHOD OF POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE ACTIVE MATERIAL POSITIVE ELECTRODE AND LITHIUM SECONDARY-BATTERY COMPRISING THE SAME

The present invention aims to provide a positive electrode active material with excellent initial capacity and initial efficiency characteristics and provides a manufacturing method of a positive electrode active material, a positive electrode active material manufactured thereby, and a positive ele...

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Bibliographische Detailangaben
Hauptverfasser: CHEONG SANG HUN, NAM JAE KEUN, KIM DONG HWAN, OH MYOUNG HWAN
Format: Patent
Sprache:eng ; kor
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Zusammenfassung:The present invention aims to provide a positive electrode active material with excellent initial capacity and initial efficiency characteristics and provides a manufacturing method of a positive electrode active material, a positive electrode active material manufactured thereby, and a positive electrode and a lithium secondary battery comprising the same, wherein the manufacturing method of a positive electrode active material comprises: a step (A) of mixing a positive electrode active material precursor with a lithium-containing raw material to manufacture a mixture and firing the mixture to manufacture a fired product; and a step (B) of washing the fired product with a cleaning solution and drying the same to manufacture a lithium transition metal oxide. The firing is performed under an oxygen atmosphere of 90 volume% of oxygen concentrations. From a time when 55 - 85 % of the entire firing time goes by, the firing is performed under an oxygen atmosphere of 20-60 volume% of oxygen concentrations. 본 발명은 초기 용량 및 초기 효율 특성이 우수한 양극 활물질을 제공하기 위한 것으로, (A) 양극 활물질 전구체와 리튬 함유 원료 물질을 혼합하여 혼합물을 제조하고, 상기 혼합물을 소성하여 소성품을 제조하는 단계; 및 (B) 상기 소성품을 수세 용액으로 수세한 후, 건조하여 리튬 전이금속 산화물을 제조하는 단계;를 포함하고, 상기 소성은 산소 농도가 90부피% 이상인 산소 분위기 하에서 수행하다가, 전체 소성 시간의 55% 내지 85%가 경과한 시점부터 산소 농도가 20부피% 내지 60부피%인 산소 분위기 하에서 수행하는 것인 양극 활물질의 제조 방법, 이러한 방법에 의해 제조된 양극 활물질, 이를 포함하는 양극 및 리튬 이차전지를 제공한다.