Aquous putty based on waterborne polyurethanes prepared by recycling waste polyethylene terephthalate

The present invention relates to a method of preparing an aqueous putty. The method of the present invention comprises: depolymerizing waste PET by using diethylene glycol and performing a glycolysis reaction, thereby obtaining a polyester polyol with a molecular weight of 500 to 3,000 g/mol; making...

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Bibliographische Detailangaben
Hauptverfasser: LEE, DAE IL, NA, BANG JU, YOO, HONG GEUN
Format: Patent
Sprache:eng ; kor
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Beschreibung
Zusammenfassung:The present invention relates to a method of preparing an aqueous putty. The method of the present invention comprises: depolymerizing waste PET by using diethylene glycol and performing a glycolysis reaction, thereby obtaining a polyester polyol with a molecular weight of 500 to 3,000 g/mol; making the polyester polyol react with dimethylol propionic acid and isophorone diisocyanate to prepare a solid of water-dispersible polyurethane; and adding calcium carbonate, fumed silica, an antifoaming agent and glycidyl propyl trimethoxy silane to the solid of water-dispersible polyurethane, thereby preparing the aqueous putty. Therefore, the method is environmentally friendly since the aqueous putty does not generate volatile components harmful to the human body such as volatile organic compounds (VOC) during use of the aqueous putty, and enables the aqueous putty to retain prompt drying capability, adhesive strength and adhesion force that do not fall behind an existing oil-based putty at the same time. 본 발명은 수성 퍼티의 제조방법에 관한 것이다. 본 발명은 디에틸렌글리콜을 이용하여 글리콜리시스 반응으로 폐 PET를 해중합함으로써, 분자량이 500~3,000 그램/몰인 폴리에스테르 폴리올을 얻고; 상기 폴리에스테르 폴리올과 dimethylol propionic acid 및 isophorone diisocyanate를 반응시켜 수분산 폴리우레탄의 고형분을 제조한 다음; 상기 수분산 폴리우레탄의 고형분에 대하여 탄산캄슘과, 퓸드 실리카와, 소포제와, Glycidyl propyl trimethoxy silane을 첨가하여 제조되는 것을 특징으로 한다. 본 발명은 사용시에 VOC와 같은 인체에 유해한 휘발성 성분을 발생시키지 않으므로 친환경적이며, 그와 동시에 종래의 유성 퍼티에 뒤지지 않는 신속한 건조능력과 접착강도 및 부착력을 보유하고 있다.