PREPARATION OF MULTIMODAL POLYETHYLENE

Disclosed is a polyethylene composition. The composition comprises single-site multimodal resin A and single-site multimodal resin B, wherein resin A differs from resin B in molecular weight, in monomeric composition, in density, in long chain branch concentration or distribution, or in combinations...

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Bibliographische Detailangaben
Hauptverfasser: MERRICK MACK JEAN A, CHANDRASHEKAR VENKI, MACK MARK P, VARGAS EDWARD S, HOLLAND CHARLES S, NAGY NATALIA, NAGY SANDOR M, GATES JR. CHARLES H
Format: Patent
Sprache:eng
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Zusammenfassung:Disclosed is a polyethylene composition. The composition comprises single-site multimodal resin A and single-site multimodal resin B, wherein resin A differs from resin B in molecular weight, in monomeric composition, in density, in long chain branch concentration or distribution, or in combinations thereof. Disclosed is also a method for making the polyethylene composition. The method comprises polymerizing, in the presence of two or more single-site catalysts, ethylene or its mixture with a C3-C10 alpha-olefin to form a first multimodal resin and continuing the polymerization in the presence of the same catalysts but in a different hydrogen concentration, in a different monomer composition, or at a different temperature to form a second multimodal resin.