CATALYSTS FOR CYCLOALKANES OXIDATION AND DECOMPOSITION OF CYCLOALKYL HYDROPEROXIDE

CATALYSTS FOR CYCLOALKANES OXIDATION AND DECOMPOSITION OF CYCLOALKYL HYDROPEROXIDE

A cyclic ketone/alcohol mixture is prepared by catalytic oxidation of the corresponding cycloalkane or catalytic decomposition of the corresponding cycloalkyl hydroperoxide. Gold supported on a porous crystalline silicate containing less than about 2 wt. % aluminum or a crystalline phosphate is used...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: URIARTE ANTHONY K, KHRAMOV MIKHAIL L, KHARITONOV ALEXANDER S, PIRUTKO LANSA V
Format: Patent
Sprache:eng
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:A cyclic ketone/alcohol mixture is prepared by catalytic oxidation of the corresponding cycloalkane or catalytic decomposition of the corresponding cycloalkyl hydroperoxide. Gold supported on a porous crystalline silicate containing less than about 2 wt. % aluminum or a crystalline phosphate is used as a catalyst. The support material optionally contains one or more heteroatoms.