PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS

A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (e) an unsymmetrical bidentate diphosphine ligand of formula (I), R1R2 > P1 - R3 - P...

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Bibliographische Detailangaben
Hauptverfasser:	ERNST RENE, DRENT EIT, JAGER WILLEM WABE, PUGH ROBERT IAN
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (e) an unsymmetrical bidentate diphosphine ligand of formula (I), R1R2 > P1 - R3 - P2 < R4R5 (I) wherein P1 andp P2 represent phosphorus atoms; R3 represents a divalent organic bridging group; and R1, R2, R4 and R5 each individually, or Rl and R2 jointly, and/or R4 and R5 jointly represent organic groups that are covalently linked to the phosphorus; and wherein R1, R2, R 4 and R5 are chosen in such way, that the phosphino group R1R2 > P1 differs from the phosphino group P2 < R4R5.