METHOD OF MANUFACTURE OF AN ELECTRODE FOR ELECTROCHEMICAL DEVICES

Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte co...

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Hauptverfasser: TIMONOV MIKHAILOVICH ALEXANDER, PAVLOV VALENTINOVICH VALERIY, LOGVINOV ANATOLIJEVICH SERGEY, KOGAN SAM, VASILJEVA VIKTOROVNA SVETLANA, SHKOLNIK NIK, LYUBOMIRSKIY ALEXANDER, PIVUNOV IVANOVICH DMITRIY
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creator TIMONOV MIKHAILOVICH ALEXANDER
PAVLOV VALENTINOVICH VALERIY
LOGVINOV ANATOLIJEVICH SERGEY
KOGAN SAM
VASILJEVA VIKTOROVNA SVETLANA
SHKOLNIK NIK
LYUBOMIRSKIY ALEXANDER
PIVUNOV IVANOVICH DMITRIY
description Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte containins an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/I within the range of potentials from -3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5x10'5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)- ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.
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subjects BASIC ELECTRIC ELEMENTS
CAPACITORS
CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES ORLIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
ELECTRICITY
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
title METHOD OF MANUFACTURE OF AN ELECTRODE FOR ELECTROCHEMICAL DEVICES
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