METHOD OF MANUFACTURE OF AN ELECTRODE FOR ELECTROCHEMICAL DEVICES

Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte co...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	TIMONOV MIKHAILOVICH ALEXANDER, PAVLOV VALENTINOVICH VALERIY, LOGVINOV ANATOLIJEVICH SERGEY, KOGAN SAM, VASILJEVA VIKTOROVNA SVETLANA, SHKOLNIK NIK, LYUBOMIRSKIY ALEXANDER, PIVUNOV IVANOVICH DMITRIY
Format:	Patent
Sprache:	eng
Schlagworte:	BASIC ELECTRIC ELEMENTS CAPACITORS CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES ORLIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE ELECTRICITY PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Deposition of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate by electrochemical polymerization is disclosed. Said polymerization occurs at a voltage applied between the substrate and a counter-electrode, both of which are submerged into the electrolyte/ The electrolyte containins an organic solvent, compounds capable of dissolving in the solvent and forming electrochemically inactive ions at concentrations of no less than 0.01 mol/I within the range of potentials from -3.0 V to +1.5 V, and a metal complex poly-[Me(R-Salen)] dissolved at a concentration of no less than 5x10'5 mole/liter. Me is transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis(salicylaldehyde)- ethylenediamine in Schiff' s base). Deposition of the redox occurs in the electrolyte where the cations of the compounds have a diameter larger than that of the electrolyte cations of energy storing device containing the electrode.