ACID-MODIFIED NOVOLAK RESIN, MANUFACTURING METHOD THEREOF AND POSITIVE PHOTORESIST COMPOSITION CONTAINING THE SAME

Provided are an acid-modified novolac resin whose dissolution velocity to an alkali developer is controlled according to the acid modification rate, its preparation method, and a positive type photoresist composition containing the resin which is improved in development, resolution and residual film...

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Hauptverfasser: SEO, HYUN JIN, WOO, SEUNG WOO, LEE, JAE HWAN, WOO, JE SUN, CHOI, YOUNG SOO, JUNG, SANG HYUP, RYU, MI SUN, YOO, KWON YIL, CHOL, SOOK YOUNG, KIM, MIN JI, CHOI, BUM YOUNG, LEE, KEUN JOO, KIM, WOONG, JUNG, NAK CHIL, JEONG, YONG MAN, KIM, MIN SUB, PAE, YOU LEE, KIM, YOONG KEUN, CHOI, JAE LOK, HAN, CHEOL, CHA, HYUK JIN, LEE, SU HYUN
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creator SEO, HYUN JIN
WOO, SEUNG WOO
LEE, JAE HWAN
WOO, JE SUN
CHOI, YOUNG SOO
JUNG, SANG HYUP
RYU, MI SUN
YOO, KWON YIL
CHOL, SOOK YOUNG
KIM, MIN JI
CHOI, BUM YOUNG
LEE, KEUN JOO
KIM, WOONG
JUNG, NAK CHIL
JEONG, YONG MAN
KIM, MIN SUB
PAE, YOU LEE
KIM, YOONG KEUN
CHOI, JAE LOK
HAN, CHEOL
CHA, HYUK JIN
LEE, SU HYUN
description Provided are an acid-modified novolac resin whose dissolution velocity to an alkali developer is controlled according to the acid modification rate, its preparation method, and a positive type photoresist composition containing the resin which is improved in development, resolution and residual film rate. The acid-modified novolac resin is represented by the formula 1, wherein A is an aldehyde derivative; R1 to R4 are independently H or a C1-C6 alkyl group; n is an integer of 0-3; and R is an anhydride derivative selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride. Preferably the acid modification rate of the novolac resin is 5-90 %. The method comprises the steps of reacting the novolac resin represented by the formula 2 with at least one anhydride selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride in the presence of a basic catalyst.
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The acid-modified novolac resin is represented by the formula 1, wherein A is an aldehyde derivative; R1 to R4 are independently H or a C1-C6 alkyl group; n is an integer of 0-3; and R is an anhydride derivative selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride. Preferably the acid modification rate of the novolac resin is 5-90 %. The method comprises the steps of reacting the novolac resin represented by the formula 2 with at least one anhydride selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride in the presence of a basic catalyst.</description><edition>7</edition><language>eng</language><subject>CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2005</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20050324&amp;DB=EPODOC&amp;CC=KR&amp;NR=20050029055A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20050324&amp;DB=EPODOC&amp;CC=KR&amp;NR=20050029055A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>SEO, HYUN JIN</creatorcontrib><creatorcontrib>WOO, SEUNG WOO</creatorcontrib><creatorcontrib>LEE, JAE HWAN</creatorcontrib><creatorcontrib>WOO, JE SUN</creatorcontrib><creatorcontrib>CHOI, YOUNG SOO</creatorcontrib><creatorcontrib>JUNG, SANG HYUP</creatorcontrib><creatorcontrib>RYU, MI SUN</creatorcontrib><creatorcontrib>YOO, KWON YIL</creatorcontrib><creatorcontrib>CHOL, SOOK YOUNG</creatorcontrib><creatorcontrib>KIM, MIN JI</creatorcontrib><creatorcontrib>CHOI, BUM YOUNG</creatorcontrib><creatorcontrib>LEE, KEUN JOO</creatorcontrib><creatorcontrib>KIM, WOONG</creatorcontrib><creatorcontrib>JUNG, NAK CHIL</creatorcontrib><creatorcontrib>JEONG, YONG MAN</creatorcontrib><creatorcontrib>KIM, MIN SUB</creatorcontrib><creatorcontrib>PAE, YOU LEE</creatorcontrib><creatorcontrib>KIM, YOONG KEUN</creatorcontrib><creatorcontrib>CHOI, JAE LOK</creatorcontrib><creatorcontrib>HAN, CHEOL</creatorcontrib><creatorcontrib>CHA, HYUK JIN</creatorcontrib><creatorcontrib>LEE, SU HYUN</creatorcontrib><title>ACID-MODIFIED NOVOLAK RESIN, MANUFACTURING METHOD THEREOF AND POSITIVE PHOTORESIST COMPOSITION CONTAINING THE SAME</title><description>Provided are an acid-modified novolac resin whose dissolution velocity to an alkali developer is controlled according to the acid modification rate, its preparation method, and a positive type photoresist composition containing the resin which is improved in development, resolution and residual film rate. 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The acid-modified novolac resin is represented by the formula 1, wherein A is an aldehyde derivative; R1 to R4 are independently H or a C1-C6 alkyl group; n is an integer of 0-3; and R is an anhydride derivative selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride. Preferably the acid modification rate of the novolac resin is 5-90 %. The method comprises the steps of reacting the novolac resin represented by the formula 2 with at least one anhydride selected from the group consisting of phthalic anhydride, succinic anhydride and maleic anhydride in the presence of a basic catalyst.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title ACID-MODIFIED NOVOLAK RESIN, MANUFACTURING METHOD THEREOF AND POSITIVE PHOTORESIST COMPOSITION CONTAINING THE SAME
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