Lithium battery with improved safety

PURPOSE: A lithium battery is provided, to improve the stability of a battery without deterioration of the battery performance by employing a pack containing a stability improving material which discharges a material for inhibiting the exothermic reaction of a battery in the case of abnormal exother...

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Bibliographische Detailangaben
1. Verfasser: HAN, GYU NAM
Format: Patent
Sprache:eng ; kor
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Zusammenfassung:PURPOSE: A lithium battery is provided, to improve the stability of a battery without deterioration of the battery performance by employing a pack containing a stability improving material which discharges a material for inhibiting the exothermic reaction of a battery in the case of abnormal exothermic reaction. CONSTITUTION: The lithium battery comprises a cathode; an anode; a separator positioned between the cathode and the anode; an organic electrolyte solution; and a pack made of a polymer film which is molten at a temperature of 90-130 deg.C and does not react with the organic electrolyte solution, where a stability improving material for inhibiting the abnormal exothermic reaction of a battery is contained by an amount of 5-30 wt% based on the total weight of the organic electrolyte solution. Preferably the stability improving material is at least one selected from the group consisting of a phosphate-based compound, a phosphorane-based compound, a cyclophosphazene-based compound, a sulfide-based compound, a silane-based compound, a fluorinated carbonate-based compound and a fluorinated polyether-based compound. 본 발명은, 캐소드, 애노드, 이들 사이에 개재되는 세퍼레이터, 및 유기전해액을 포함하는 리튬전지에 있어서, 상기 유기전해액과의 반응성이 없으며 90∼130℃에서 용융되는 고분자 필름으로 이루어진 포장재 내에 전지의 이상 발열 반응을 억제하는 안전성 향성 물질이 상기 유기전해액의 총중량을 기준으로 5 ∼ 30 중량% 밀봉되어 있는 팩을 포함하는 것을 특징으로 하는 리튬 전지를 제공한다. 본 발명에 따라 제조된 전지는 전지 내부에 발열반응을 억제하는 안전성 향상 물질을 내장하는 팩을 전지 내부에 포함하고 있고, 이 물질은 전지의 정상 작동시에는 전지 성능에 아무런 영향을 미치지 않으나, 비상시에는 내부의 안전성 향상 물질이 팩으로부터 방출되어 이상 발열 반응을 억제함으로써 전지의 안전성을 향상시킨다.