A METHOD FOR MANUFACTURING A FUNCTIONALIZED HIGH-CIS POLYDIENE

The present invention provides a method for producing functional high-cis polydiene, comprising the following steps of: (a) making a diene monomer react with one or more compounds represented by chemical formulas 1-3 in the presence of a catalyst; and (b) further polymerizing a diene monomer with th...

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Bibliographische Detailangaben
Hauptverfasser:	LEE, SEUNG HWON, LEE, HAN BAEK, KIM, HOO CHAE, DO, SEUNG HYUN, KWAG, GWANG HOON, KANG, DONG EUN
Format:	Patent
Sprache:	eng ; kor
Schlagworte:	CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP
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Beschreibung
Zusammenfassung:	The present invention provides a method for producing functional high-cis polydiene, comprising the following steps of: (a) making a diene monomer react with one or more compounds represented by chemical formulas 1-3 in the presence of a catalyst; and (b) further polymerizing a diene monomer with the product in the step (a). In the chemical formulas 1-3, R_1 to R_3 are as described in the present invention. According to one aspect of the present invention, the method can improve affinity to and compatibility with fillers. 본 발명의 일 실시예는 (a) 촉매 존재 하에서 디엔 단량체 및 하기 화학식 1 내지 화학식 3으로 표시되는 화합물 중 하나 이상을 반응시키는 단계; 및 (b) 상기 (a) 단계의 생성물에 디엔 단량체를 추가로 중합하는 단계;를 포함하는 관능성 고시스 폴리디엔의 제조방법을 제공한다. 상기 식에서, R내지 R는 각각 C내지 C의 알킬기, 아릴기, 알콕시기, -NR'R'', -SiR'R''R''' 또는 수소이고, R', R'', R'''는 각각 C내지 C의 알킬기, 아릴기, 알콕시기 또는 수소이고, Z은 실리콘, 주석, 질소, 산소, 황, 인, 탄소 또는 수소이고, A은 C내지 C의 알킬렌기 또는 아릴렌기이고, n은 1 내지 20의 정수 중 하나이다.