PROCESS FOR DESULFURIZING CATALYTICALLY CRACKED GASOLINE

A process for desulfurizing catalytically cracked gasoline containing sulfur compounds and olefin components, which comprises the steps of: 1) first desulfurizing the catalytically cracked gasoline in the presence of a hydrodesulfurization catalyst at a desulfurization rate of 60 to 90%, a reaction...

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Bibliographische Detailangaben
Hauptverfasser:	SADAKANE, OSAMU, MIYAMA, TADAO, HATANAKA, SHIGETO, HIKITA, SATORU
Format:	Patent
Sprache:	eng
Schlagworte:	APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS GENERAL METHODS OF ORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	A process for desulfurizing catalytically cracked gasoline containing sulfur compounds and olefin components, which comprises the steps of: 1) first desulfurizing the catalytically cracked gasoline in the presence of a hydrodesulfurization catalyst at a desulfurization rate of 60 to 90%, a reaction temperature of 200 to 350 DEG C, a hydrogen partial pressure of 5 to 30 kg/cm , a hydrogen/oil ratio of 500 to 3,000 scf/bbl, and a liquid hourly space velocity of 2 to 10 1/hr, said first desulfuriing step comprising supplying a feed having a hydrogen sulfide vapor concentration of not more than 0.1% by volume, and 2) next desulfurizing the treated oil obtained in the first step in the presence of a hydrodesulfurization catalyst at a desulfurization rate of 60 to 90%, a reaction temperature of 200 to 300 DEG C, a hydrogen partial pressure of 5 to 15 kg/cm , a hydrogen/oil ratio of 1,000 to 3,000 scf/bbl, and a liquid hourly space velocity of 2 to 10 1/hr, said second desulfurizing step comprising supplying a feed having a hydrogen sulfide vapor concentration of not more than 0.05% by volume. A reduction in octane number due to hydrogenation of olefin components is minimized while achieving a high desulfurization rate.