COAL LIQUEFACTION WITH COMPLEX CATALYST

PURPOSE:To increase the conversion of coal efficiently and the amount of hydrogen added, by carrying out coal liquefaction reaction using an iron sulfide- sulfate or sulfate group-bearing iron oxide complex catalyst. CONSTITUTION:For example, (A) coal, (B) a solvent such as tetralin or 1-methyl- nap...

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Hauptverfasser: YAMAMOTO MITSUYOSHI, NARITA HIDEO, MAEKAWA WAKUNORI, YOKOYAMA SHINICHI, KOTANIGAWA TAKESHI
Format: Patent
Sprache:eng
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Zusammenfassung:PURPOSE:To increase the conversion of coal efficiently and the amount of hydrogen added, by carrying out coal liquefaction reaction using an iron sulfide- sulfate or sulfate group-bearing iron oxide complex catalyst. CONSTITUTION:For example, (A) coal, (B) a solvent such as tetralin or 1-methyl- naphthalene, (C) an iron sulfide-sulfate, or sulfate group-bearing iron oxide complex catalyst and (D) a gas mixture of hydrogen, nitrogen and others are charged in an autoclave. The temperature is raised from room temperature at a rate of 2.5 deg.C/min, and reaching 450 deg.C, the autoclave is rapidly cooled down whereby the coal is liquefied.