PRESSURE-SENSITIVE ADHESIVE

PURPOSE:To obtain a pressure-sensitive adhesive having excellent restrippability and suitable for use as a masking material, etc., by using a graft polymer having a main chain composed of a specific acrylic ester and side chains composed of a specific high-molecular compd. and a side-chain forming c...

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1. Verfasser: ONISHI HIROHITO
Format: Patent
Sprache:eng
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Zusammenfassung:PURPOSE:To obtain a pressure-sensitive adhesive having excellent restrippability and suitable for use as a masking material, etc., by using a graft polymer having a main chain composed of a specific acrylic ester and side chains composed of a specific high-molecular compd. and a side-chain forming compd. as components. CONSTITUTION:A pressure-sensitive adhesive comprises a graft polymer having a main chain composed of an acrylic polymer having a glass transition point not higher than 0 deg.C and composed of at least 50wt.% acrylic ester obtd. by using a 14C or lower primary or secondary alcohol and side chains composed of a compd. having a weight-average MW of 1,000 or above and an SP value wherein a difference in the SP value between the main chain and the side chain is 6 or smaller and 1-30pts.wt. (per 100pts.wt. graft polymer) side chain forming compd. The alcohol component in the acrylic ester or esters for the acrylic polymer has an average carbon atom number of pref. 4-12 from the viewpoint of the flexibility of the acrylic polymer. The SP value is determined from a formula representing the total value (SIGMAFi) of gram molecule suction constant/the total value (SIGMAVi) of gram molecule volume.