DISPROPORTIONATION OF SILANES

DISPROPORTIONATION OF SILANES

PURPOSE:To obtain a silane compound useful for high-purity silicone, etc., industrially and advantageously, by bringing a specific silane containing a Si-H bond into contact with a reaction product of a sulfonic acid of polyorganosiloxane skeleton and an amine compound to carry out disproportionatio...

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Hauptverfasser: YANAGAWA NORIYUKI, INOUE KAORU, MURAKAMI MASAMI, MIYAGAWA HIROJI, ITO MASAYOSHI
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Sprache:eng
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ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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creator YANAGAWA NORIYUKI
INOUE KAORU
MURAKAMI MASAMI
MIYAGAWA HIROJI
ITO MASAYOSHI
description PURPOSE:To obtain a silane compound useful for high-purity silicone, etc., industrially and advantageously, by bringing a specific silane containing a Si-H bond into contact with a reaction product of a sulfonic acid of polyorganosiloxane skeleton and an amine compound to carry out disproportionation reaction. CONSTITUTION:A silane (e.g. trichlorosilane, etc.) shown by the formula (R is aliphatic group or aromatic group; X is halogen, alkoxy or aryloxy; l is 0-2 integer; m is 1-3 integer; l+m is 1-3 integer) containing at least one Si-H bond is brought into contact with a reaction product of a sulfonic acid of polyorganosiloxane skeleton and an amine compound (e.g. ammonia) and subjected to disproportionation reaction at 0-400 deg.C to give the aimed compound.
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title DISPROPORTIONATION OF SILANES
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