PRODUCTION OF TETRAETHYLUREA

PURPOSE:To obtain a compound useful as a synthetic raw material for high polymers, medicines, agricultural chemicals and various organic chemicals in good yield, by reacting diethylamine with carbon dioxide in the presence of a palladium based catalyst in a solvent, e.g. carbon tetrachloride, etc. C...

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Bibliographische Detailangaben
Hauptverfasser:	YAMATO MICHIO, MORIMOTO YOSHIAKI, TANIGUCHI HIROSHI, FUJIWARA YUZO
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	PURPOSE:To obtain a compound useful as a synthetic raw material for high polymers, medicines, agricultural chemicals and various organic chemicals in good yield, by reacting diethylamine with carbon dioxide in the presence of a palladium based catalyst in a solvent, e.g. carbon tetrachloride, etc. CONSTITUTION:Diethylamine is reacted with carbon dioxide in the presence of a palladium based catalyst, e.g. dichlorobis(triphenylphosphine)palladium, in a solvent, e.g. carbon tetrachloride or carbon tetrachloride and acetonitrile, at 10-150 deg.C under 0-100kg/cm G pressure for 10-100hr to afford the aimed substance. The solvent is used in a volume of 0.2-20l based on 1mol diethylamine and the catalyst is used in an amount of 0.005-0.100mol palladium metal atom based on 1mol diethylamine to carry out the reaction.