PRODUCTION OF CATIONIC HYDRAZONE DYE

Cationic hydrazone dyestuffs of the general formula I in which R1 stands for hydrogen, C1-C4-alkyl, C1- to C4-alkoxy, nitro or halogen, R2 stands for hydrogen, C1- to C4-alkyl, C1- to C4-alkoxy, halogen or phenylazo, R3 stands for C1- to C3-alkyl and A- stands for an anion, are prepared by quaternar...

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Hauptverfasser: HANSU ROTAARU DORUSHIYU, DEIITOMARU KARUTSU, FUORUKAA HIYUUNE, ROODERITSUHI RAUE
Format: Patent
Sprache:eng
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Zusammenfassung:Cationic hydrazone dyestuffs of the general formula I in which R1 stands for hydrogen, C1-C4-alkyl, C1- to C4-alkoxy, nitro or halogen, R2 stands for hydrogen, C1- to C4-alkyl, C1- to C4-alkoxy, halogen or phenylazo, R3 stands for C1- to C3-alkyl and A- stands for an anion, are prepared by quaternarizing azo bases of the general formula II wherein R1, R2 and R3 have the abovementioned meaning, with dialkyl sulphates of the general formula (R3-O)2SO2 III in which R3 has the abovementioned meaning, in the presence of water and alkali metal sulphate or alkaline earth metal sulphate and, where appropriate, by replacing the alkylsulphate anion by another anion.